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Pembuatan Senyawa Amina Sekunder dengan Proses Hidrogenasi Senyawa Nitril

机译:用腈加氢工艺制备仲胺化合物

摘要

The amine compounds are used excessively in chemical industry, mainly as a surfactant. Indonesia imports this compound in a large amount (14.000 tons). The secondary amine is an intermediate product of quartener amine which is known as a softener. This research is aimed to observe the chemical reaction of synthesizing secondary amine at laboratory scale.To achieve this goal, the synthesize was conducted by hydrogenating the nitrile compound in a reactor in which two levels of pressure were applied (11 and 35 bars). The reaction temperature as well as the length of reaction time were also varied i.e at 140°, 160° and 175° Cfor 3, 6 and 10 hours.The analytical results showed that at relatively low pressure (11 bars) and the reaction temperatures of 140°,160° and 175° C for 10 haurs gave products containing secondary amine as much as 48,90; 74,63 and 67,26%, respectively. The 6 hours processing time at 140°C did not produce any amine. However when temperature was increased to 160° and 175° C, the amounts of amine yielded are as follow: 46,40 and 73,33%. A higher result (85,80%) was obtained from a process conducted at reaction temperature 175° C for 3 hours.By increasing the pressure up to 35 bars and the reaction was maintained at 160°, 83,40% amine was produced in 1 hour only. This finding indicated that producing amine at lower pressure required longer processing time.
机译:胺化合物在化学工业中过量使用,主要用作表面活性剂。印度尼西亚大量进口了该化合物(1.4万吨)。仲胺是四元胺的中间产物,被称为软化剂。这项研究的目的是在实验室规模下观察合成仲胺的化学反应。为了实现这一目标,在加有两个压力等级(11和35 bar)的反应器中氢化腈化合物进行合成。反应温度以及反应时间的长短也发生了变化,即分别在140°C,160°C和175°C下持续了3、6和10小时。分析结果表明,在相对较低的压力(11巴)下,反应温度为在140°,160°和175°C下加热10小时,得到的仲胺含量高达48,90;分别为74.63和67.26%。在140℃下6小时的处理时间没有产生任何胺。但是,当温度升至160°C和175°C时,胺的产生量如下:46.40%和73.33%。通过在175°C的反应温度下进行3小时的过程获得了更高的结果(85,80%)。通过将压力提高到35巴并将反应保持在160°C,在反应器中生成了83.40%的胺。仅1小时。该发现表明在较低压力下生产胺需要更长的处理时间。

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